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Is Stainless Steel Magnetic?

by | May 8, 2024

Stainless steel is a popular metal alloy favoured for its durability, resistance to corrosion, and aesthetic appeal. However, there is often confusion about whether it is magnetic. The truth is, it depends on the type of stainless steel.

The term “stainless steel” covers a range of metals, each with different properties and chemical compositions. Some types of stainless steel are magnetic, while others are not. This variation is primarily due to the different structures and elements used in manufacturing the various types of stainless steel. For example, stainless steel types that contain more iron are generally magnetic, whereas those with higher chromium and nickel content usually aren’t.

Understanding this helps in selecting the right type of stainless steel for specific applications, particularly where magnetism might be a factor or concern.

What is the difference between Steel and Stainless Steel?

Regular steel, also known as carbon steel, is primarily made from iron and carbon, with small amounts of other elements like manganese, sulfur, phosphorus, and silicon. These elements give steel its basic strength and formability, making it useful in a variety of applications from construction to tools.

Stainless steel, on the other hand, contains a significant amount of chromium—usually at least 10.5% by weight. This chromium is what sets stainless steel apart. It reacts with oxygen in the air to form a thin, protective layer on the surface of the steel. This layer shields the material from rust and corrosion, which is why stainless steel is famous for its longevity and glossy appearance. Stainless steel may also include other elements like nickel, molybdenum, or manganese, which can enhance its strength, durability, and resistance to high temperatures.

These additional elements make stainless steel ideal for more demanding environments, such as kitchen appliances, medical instruments, and automotive parts, where regular steel might deteriorate quickly. Thus, while both materials are essential in their own right, choosing between them depends largely on the specific needs of the application.

Types and Grades of Stainless Steel

Stainless steel comes in various types and grades, each tailored to specific uses. Pinning down an exact number of all the stainless steel grades is challenging because new ones are constantly being developed, and existing grades are often adapted for specific purposes or preferences. However, there are thousands of stainless steel grades documented globally, with some being more commonly used than others.

To understand stainless steel better, especially regarding its magnetic properties, we can categorise it into a few main types:

Ferritic Stainless Steel

Ferritic stainless steel is known for its magnetic properties, due to its high ferrite content. It generally has good corrosion resistance, especially in mild environments, and is mainly composed of iron and chromium, typically around 17% chromium, as seen in the commonly used Grade 430. It may also include small amounts of manganese and silicon.

Austenitic Stainless Steel

In contrast, austenitic stainless steel is typically non-magnetic and is highly prized for its excellent corrosion resistance, ductility, and formability. This group includes iron, chromium, and nickel; common grades like 304 and 316 usually contain about 18% chromium and 8-10% nickel. The addition of nickel stabilises the austenite structure, enhancing the steel’s overall performance.

Martensitic Stainless Steel

Martensitic stainless steel is magnetic and known for its strength and hardness. It is ideal for applications requiring resistance to wear and can be hardened through heat treatment. This type of steel is primarily made up of iron, chromium, and carbon, with Grade 410 containing about 12% chromium and 0.15% carbon.

Duplex Stainless Steel

Duplex stainless steel combines the qualities of both austenitic and ferritic stainless steels, resulting in increased strength and excellent corrosion resistance. A popular choice is Grade 2205, which consists of iron, chromium, nickel, and a significant amount of nitrogen to boost its corrosion-resistant properties.

Precipitation Hardening Stainless Steel

Lastly, precipitation-hardening stainless steels offer high strength and corrosion resistance, achieved through heat treatment. These are typically used in aerospace and other high-performance applications. Grade 17-4 PH is a common example, comprising iron, chromium, nickel, and copper, with additional elements like niobium and molybdenum for hardening.

Each type of stainless steel has been developed to meet specific needs, making it essential to choose the right grade for your application to ensure performance and durability.

What Makes Stainless Steel Magnetic?

The magnetic properties of stainless steel depend on its composition and how its atoms are arranged. Here’s a clearer explanation:

Ferritic and Martensitic Stainless Steels: These types of stainless steel are magnetic. They have a structure primarily made up of ferrite, which is a magnetic phase of iron. Ferritic steels, such as Grade 430, contain chromium and sometimes elements like nickel or molybdenum. Martensitic steels, like Grade 410, are similar but are also designed to be hardened through heat treatment, enhancing their strength.

Austenitic Stainless Steels: These are the most common types of stainless steel, such as Grades 304 and 316, and are typically non-magnetic when in their standard (annealed) state. This is due to their austenitic structure, which does not naturally interact with magnetic fields. They contain higher amounts of nickel and sometimes manganese, in addition to chromium.

Precipitation Hardening Stainless Steel: This type of steel, like Grade 17-4 PH, can be non-magnetic in its softened state but may become slightly magnetic after undergoing an ageing process known as precipitation hardening. This process strengthens the steel by forming tiny, dispersed particles within the steel matrix.

Duplex Stainless Steel: These steels combine features of both austenitic and ferritic stainless steels, resulting in both strength and corrosion resistance. The microstructure of duplex steel includes both austenitic and ferritic phases, which means it can show varying degrees of magnetism. Generally, duplex steels are more magnetic than austenitic types but less so than ferritic or martensitic steels.

It’s important to understand that although austenitic stainless steels are usually non-magnetic, they can become slightly magnetic when subjected to cold working. Cold working refers to processes like bending or machining, which put stress on the steel. This stress can change the steel’s internal structure slightly, mixing in some magnetic properties through the creation of a new phase called martensite alongside the original austenite. This transformation can make the steel weakly magnetic.

In summary, whether stainless steel is magnetic or not depends largely on its specific alloy composition and how it is processed.

FAQs

Can a magnet stick to stainless steel?

Yes and no. Magnets can stick to some types of stainless steel but not to all. Generally, stainless steel isn’t very magnetic, but certain types contain enough iron to be attracted to a magnet. The type most likely to be magnetic is called ferritic stainless steel. Martensitic stainless steel can also be magnetic, depending on its composition and how it’s processed. However, the most common type, austenitic stainless steel, usually isn’t magnetic. So, whether a magnet sticks to stainless steel depends on the specific type used.

What stainless steel is not magnetic?

The most commonly non-magnetic stainless steel is austenitic. This type usually includes elements like iron, chromium, nickel, and sometimes manganese or nitrogen. It’s non-magnetic in its annealed (softened) state. Common grades like 304 and 316 fall into this category and are used in everything from kitchen appliances to medical equipment and building structures.

Why don't magnets stick to my stainless steel refrigerator?

If magnets don’t stick to your refrigerator, it’s probably made of austenitic stainless steel, which is non-magnetic. This type of steel contains nickel and has a specific arrangement of atoms that doesn’t support magnetic attraction. However, if a fridge is magnetic, it might be made of either ferritic or martensitic stainless steel, both of which are magnetic. So, if your refrigerator doesn’t attract magnets, it’s likely made from austenitic stainless steel.

Do magnets stick to 316 stainless steel?

Magnets typically do not stick to 316 stainless steel. This austenitic alloy includes elements like nickel and molybdenum alongside iron and chromium, which enhance its corrosion resistance, making it ideal for harsh environments like marine or chemical processing sectors. This composition also means it’s generally non-magnetic.

Which Steel grades are magnetic and which are not?

Here’s a straightforward look at some common grades of stainless steel, sorted by their magnetic properties:

Magnetic Stainless Steels:

  1. Ferritic Stainless Steel
    • Grade 430: Moderately magnetic (similar in magnetic properties to plain iron)
    • Grade 446: Moderately magnetic
  2. Martensitic Stainless Steel
    • Grade 410: Strongly magnetic (high iron content enhances magnetic properties)
    • Grade 420: Strongly magnetic
    • Grade 440: Strongly magnetic

Non-Magnetic Stainless Steels:

  1. Austenitic Stainless Steel
    • Grade 304: Generally non-magnetic in the annealed state but can become slightly magnetic when cold worked
    • Grade 316: Generally non-magnetic in the annealed state but can become slightly magnetic when cold worked
    • Grade 302: Non-magnetic in the annealed state, slightly magnetic when cold worked
  2. Duplex Stainless Steel
    • Grade 2205: Weakly magnetic due to its mixed microstructure of austenite and ferrite
  3. Precipitation Hardening Stainless Steel
    • Grade 17-4 PH: Non-magnetic in the solution-annealed state but can become weakly magnetic after being heat treated

This summary explains how the magnetic properties of different steel types depend on their makeup and structure. Ferritic and martensitic steels, which contain more iron, are typically more magnetic. In contrast, austenitic and some types of duplex steels generally show weaker magnetic qualities. The magnetism of precipitation hardening steels, however, can change depending on the specific heat treatment they undergo. This variety means that the magnetic response of stainless steel can vary widely depending on the specific alloy and its treatment.

 

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